BBr3-Assisted Cleavage of Most Ethers Does Not Follow the Commonly Assumed Mechanism
نویسندگان
چکیده
منابع مشابه
Ether Cleavage Re-Investigated: Elucidating the Mechanism of BBr3-Facilitated Demethylation of Aryl Methyl Ethers
One of the most well-known, highly utilized reagents for ether cleavage is boron tribromide (BBr3), and this reagent is frequently employed in a 1:1 stoichiometric ratio with ethers. Density functional theory calculations predict a new mechanistic pathway involving charged intermediates for ether cleavage in aryl methyl ethers. Moreover, these calculations predict that one equivalent of BBr3 ca...
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ژورنال
عنوان ژورنال: European Journal of Organic Chemistry
سال: 2013
ISSN: 1434-193X
DOI: 10.1002/ejoc.201300337